Kajian Awal Sintesis Reduced Graphene Oxide (rGO) Metode Iradiasi Microwave dan Ultrasonikasi

Preliminary Study of Microwave Irradiation and Ultrasonic Reduced Graphene Oxide (rGO) Synthesis

  • Titin Aryani Fakultas Ilmu Kesehatan, Universitas ‘Aisyiyah Yogyakarta, Jl. Siliwangi No.63, Mlangi, Nogotirto, Sleman, D.I Yogyakarta, 55292 2
  • Isnin Aulia Ulfah Mu’awanah Fakultas Ilmu Kesehatan, Universitas ‘Aisyiyah Yogyakarta, Jl. Siliwangi No.63, Mlangi, Nogotirto, Sleman, D.I Yogyakarta, 55292 2
Keywords: Reduced Graphene Oxide, Microwave, Ultrasonikasi

Abstract

Grafena merupakan material yang banyak digunakan pada berbagai aplikasi. Salah satu bentuk grafena yang banyak disintesis adalah reduced Graphene Oxide (rGO). Metode sintesis grafena telah banyak dipelajari. Umumnya sintesis grafena dilakukan dalam beberapa tahap yang merupakan metode kombinasi. Salah satu cara untuk menilai hasil sintesis adalah melakukan karakterisasi berdasarkan absorbansi grafena menggunakan spektrofotometri Uv-Vis. Pada penelitian ini telah dilakukan sintesis grafena menggunakan iradiasi  microwave dan ultrasonikasi. Hasil penelitian menunjukkan bahwa metode iradiasi  microwave dan ultrasonikasi menggunakan bahan grafit tereksfoilasi memberikan serapan absorbansi terbaik yang spesifik menunjukkan karakter rGO dibandingkan serbuk grafit. Kesimpulan dari penelitian ini adalah berdasarkan karakterisasi rGO menggunakan spektrofotometri Uv-Vis, grafit tereksfoilasi merupakan bahan yang lebih baik dibandingkan grafit tanpa eksfoilasi untuk digunakan dalam sintesis rGO menggunakan metode iradiasi  microwave dan ultrasonikasi karena memberikan puncak yang spesifik untuk rGO pada panjang gelombang 266 nm.

References

Chen, Xiaoxiao, dan Baoliang Chen. 2015. Macroscopic and Spectroscopic Investigations of the Adsorption of Nitroaromatic Compounds on Graphene Oxide, Reduced Graphene Oxide, and Graphene Nanosheets. Environmental Science & Technology. 49 (10): 6181–89.

Gebreegziabher, G.G., A.S. Asemahegne, D.W. Ayele, M. Dhakshnamoorthy, A. Kumar. 2019. One-Step Synthesis and Characterization of Reduced Graphene Oxide Using Chemical Exfoliation Method. Materials Today Chemistry. 12 (June): 233–39.

Huang, Nay Ming. 2011. Simple Room-Temperature Preparation of High-Yield Large-Area Graphene Oxide. International Journal of Nanomedicine, December, 3443.

Hummers, William S., dan Richard E. Offeman. 1958. Preparation of Graphitic Oxide. Journal of the American Chemical Society. 80 (6): 1339–1339.

Lee, Xin Jiat, Billie Yan Zhang Hiew, Kar Chiew Lai, Lai Yee Lee, Suyin Gan, Suchithra Thangalazhy-Gopakumar, Sean Rigby. 2019. Review on Graphene and Its Derivatives: Synthesis Methods and Potential Industrial Implementation. Journal of the Taiwan Institute of Chemical Engineers. 98: 163–80. Mei 2019.

Loryuenyong, Vorrada, Krit Totepvimarn, Passakorn Eimburanapravat, Wanchai Boonchompoo, Achanai Buasri. 2013. Preparation and Characterization of Reduced Graphene Oxide Sheets via Water-Based Exfoliation and Reduction Methods. Advances in Materials Science and Engineering. 1–5.

Majumdar, D. 2017. Hydroxy-Functionalized Graphene : A Proficient Energy Storage Material. Fundam Renewable Energy Appl. 6(3): 1-5.

Marcano, Daniela C., Dmitry V. Kosynkin, Jacob M. Berlin, Alexander Sinitskii, Zhengzong Sun, Alexander Slesarev, Lawrence B. Alemany, Wei Lu, James M. Tour. 2010. Improved Synthesis of Graphene Oxide. ACS Nano. 4 (8): 4806–14.

Rattana, T., Chaiyakun, S., Witit-Anun, N., Nuntawong, N., Chindaudom, P., Oaew, S., Kedkeaw, C., and Limsuwan, P. 2012. Preparation and characterization of graphene oxide nanosheets. Procedia Eng. 32: 759–764.

Sykam N. , Naidu D.J, Mohan R. 2018. Highly effiffifficient removal of toxic organic dyes, chemical solvents and oils by mesoporous exfoliated graphite: Synthesis and mechanism. Journal of Water Process Engineering. 25 (2018) 128–137

Su, Ching-Yuan, Yanping Xu, Wenjing Zhang, Jianwen Zhao, Aiping Liu, Xiaohong Tang, Chuen-Horng Tsai, Yizhong Huang, Lain-Jong Li. 2010. Highly Efficient Restoration of Graphitic Structure in Graphene Oxide Using Alcohol Vapors. ACS Nano. 4 (9): 5285–92.

Zaaba, N.I., K.L. Foo, U. Hashim, S.J. Tan, Wei-Wen Liu, C.H. Voon. 2017. Synthesis of Graphene Oxide Using Modified Hummers Method: Solvent Influence. Procedia Engineering. 184: 469–77.

Published
2023-08-15
Section
Artikel Penelitian